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Ants Tuulmets

https://www.etis.ee/CV/Ants_Tuulmets/est
7.02.1936
737 5238
ants.tuulmets@ut.ee

Teenistuskäik

Haridustee
Tartu Ülikool ( kiitusega ) 1959 , keemik
1959-1962 Tartu Ulikooli aspirantuur füüsikalise keemia alal
 
 
Teadusorganisatsiooniline ja -administratiivne tegevus
Ameerika Keemia Seltsi liige (1998), Euroopa Sonokeemia Seltsi liige (1994)
Mitme teadusajakirja referee.

Kvalifikatsioon

Teaduskraadid
Ants Tuulmets, doktorikraad, 1975, (juh) -, Quantitative investigation of the interaction of organomagnesium compounds with ketones ( in Russian ), Tartu Ülikool.
 
 
Teaduspreemiad ja tunnustused
2001, Ants Tuulmets, Tartu Ülikooli medal
1993, Ants Tuulmets, ISF (Soros Foundation) toetus
1989, Ants Tuulmets, – Eesti Teaduste Akadeemia Paul Kogermani medal
 
 
Teadustöö põhisuunad
ETIS KLASSIFIKAATOR: 4. Loodusteadused ja tehnika; 4.11. Keemia ja keemiatehnika; TÄPSUSTUS: Kinetics and mechanism of the Grignard reaction with silanes. Solvent effects in organometallic chemistry. Sonochemistry of polar homogeneous reactions.
 
 
Lisainfo
Candidate of chemical sciences (PhD), 1965
University of Tartu
Doctor of Sciences ( in chemistry), 1975
University of Tartu

Juhendatud väitekirjad

Publikatsioonid

Klass
Aasta
Publikatsioon
 
1.1.
2007
Golubev, O.; Panov, D.; Ploom, A.; Tuulmets, A.; Nguyen, Binh T. (2007). Quantitative substituent effects in the Grignard reaction with silanes. Journal of Organometallic Chemistry, 692 (17), 3700−3705. DOI: 10.1016/j.jorganchem.2007.05.009.
1.1.
2005
Simuste, H.; Panov, D.; Tuulmets, A.; Nguyen, BT. (2005). Formation of phenylmagnesium halides in toluene. Journal of Organometallic Chemistry, 690 (12), 3061−3066.
1.1.
2004
Tammiku-Taul, J.; Burk, P.; Tuulmets, A. (2004). Theoretical study of magnesium compounds: The Schlenk equilibrium in the gas phase and in the presence of Et2O and THF molecules. The Journal of Physical Chemistry A, 108 (1), 133−139.
1.1.
2004
Tuulmets, A.; Tammiku-Taul, J.; Burk, P. (2004). Computational study of the Grignard reaction with alkynes. Journal of Molecular Structure THEOCHEM, 674, 233−239.
1.1.
2004
Tuulmets, A.; Nguyen, BT.; Panov, D. (2004). Grignard reaction with chlorosilanes in THF: A kinetic study. Journal of Organic Chemistry, 69 (15), 5071−5076.
1.1.
2003
Sassian, M.; Tuulmets, A. (2003). Solvation effects in the Grignard reaction with carbonyl compounds. Helvetica Chimica Acta, 86 (1), 82−90.
1.1.
2003
Tuulmets, A.; Panov, D.; Sassian, M. (2003). On the mechanism derived from kinetic solvent effects of Grignard reactions with silanes. Tetrahedron Letters, 44 (20), 3943−3945.
1.1.
2003
Tuulmets, A.; Nguyen, BT.; Panov, D.; Sassian, M.; Jarv, J. (2003). Kinetics of the grignard reaction with silanes in diethyl ether and ether-toluene mixtures. Journal of Organic Chemistry, 68 (26), 9933−9937.
1.1.
2002
Sassian, M.; Panov, D.; Tuulmets, A. (2002). Grignard reagents in toluene solutions. Applied Organometallic Chemistry, 16 (9), 525−529.
1.1.
2002
Tuulmets, A.; Pallin, V.; Tammiku-Taul, J.; Burk, P.; Raie, K. (2002). Solvent effects in the Grignard reaction with alkynes. Journal of Physical Organic Chemistry, 15 (10), 701−705.
6.09.2021

Ants Tuulmets

https://www.etis.ee/CV/Ants_Tuulmets/eng
7.02.1936
737 5238
ants.tuulmets@ut.ee

Career

Institutions and positions
2001–...   
University of Tartu, Faculty of Science and Technology (old), Institute of Chemistry, Tartu University, Professor emeritus (1,00)
01.01.2008–31.12.2010   
University of Tartu, Faculty of Science and Technology (old), Institute of Chemistry, Tartu University, Research Fellow (1,00)
01.01.2005–31.07.2007   
University of Tartu, Faculty of Physics and Chemistry, Institute of Organic and Bioorganic Chemistry, Research Fellow extraordinarius (1,00)
2004–2004   
University of Tartu, Faculty of Physics and Chemistry, Institute of Organic and Bioorganic Chemistry, Chair of Organic Chemistry, erakorraline teadur (0,50)
1993–2001   
University of Tartu, Faculty of Physics and Chemistry, Other staff (1,00)
1992–2001   
University of Tartu, Faculty of Physics and Chemistry, Institute of Organic and Bioorganic Chemistry, Professor (1,00)
1980–1992   
University of Tartu, Faculty of Physics and Chemistry, Professor (1,00)
1975–1980   
University of Tartu, Faculty of Physics and Chemistry, Associate Professor (1,00)
1962–1975   
University of Tartu, Faculty of Physics and Chemistry, Researcher (1,00)
 
 
Education
Graduated ( cum laude ) from the University of Tartu in 1959 (chemist)
1959-1962 postgraduate studies at the University of Tartu on physical chemistry
 
 
R&D related managerial and administrative work
Member of The American Chemical Society (1998), Member of European Sonochemical Society (1994),.
Referee of a number of journals

Qualifications

Academic degrees
Ants Tuulmets, Doctor's Degree, 1975, (sup) -, Quantitative investigation of the interaction of organomagnesium compounds with ketones ( in Russian ), University of Tartu.
 
 
Honours & awards
2001, Ants Tuulmets, Medal of the University of Tartu
1993, Ants Tuulmets, ISF (Soros Foundation) award
1989, Ants Tuulmets, Paul Kogerman Medal of Estonian Academy of Sciences
 
 
Fields of research
ETIS CLASSIFICATION: 4. Natural Sciences and Engineering; 4.11. Chemistry and Chemical Technology
 
 
Additional information
Ph.D. 1965
University of Tartu
D.Sc. 1975
USSR

Completed projects

Supervised dissertations

Publications

Category
Year
Publication
 
1.1.
2015
Ploom, A.; Tuulmets, A.; Panov, D.; Burk, P. (2015). A kinetic view of the mechanism of the Grignard reaction with alkoxysilanes. Phosphorus Sulfur and Silicon and the Related Elements, 190 (4), 509−519. DOI: 10.1080/10426507.2014.952002.
1.1.
2014
Tuulmets, Ants; Piiskop, Sander; Järv, Jaak; Salmar, Siim (2014). Sonication effects on non-radical reactions. A sonochemistry beyond the cavitation? Ultrasonics Sonochemistry, 21 (3), 997−1001. DOI: 10.1016/j.ultsonch.2013.11.001.
1.1.
2013
Sander, Piiskop; Siim, Salmar; Ants, Tuulmets; Aleksei, Kuznetsov; Jaak, Järv (2013). Kinetic sonication effects in aqueous acetonitrile solutions. Reaction rate levelling by ultrasound. Ultrasonics Sonochemistry, 20 (6), 1414−1418. DOI: 10.1016/j.ultsonch.2013.03.014.
1.1.
2013
Salmar, S; Kuznetsov, A; Tuulmets, A; Järv, J; Piiskop, S. (2013). Kinetic sonication effects in light of molecular dynamics simulation of the reaction medium. Ultrasonics Sonochemistry, 20, 703−707. DOI: 10.1016/j.ultsonch.2012.10.010.
1.1.
2012
Salmar, S.; Järv, J.; Tenno, T. ; Tuulmets, A. (2012). Role of water in determining organic reactivity in aqueous binary solvents. Central European Journal of Chemistry, 10 (5), 1600−1608. DOI: 10.2478/s11532-012-0080-8.
5.2.
2012
Piiskop, S; Salmar, S; Tuulmets, A. (2012). Impact of ultrasound on some solute-solvent interactions. ESS-13: 13th Meeting of the European Society of Sonochemistry, Lviv, Ukraine, 1-5.07.2012. , 131−132.
5.2.
2012
Salmar, Siim; Kuznetsov, Aleksei; Tuulmets, Ants; Järv, Jaak; Piiskop, Sander (2012). Elucidation of Kinetic Sonication Effects by Means of Molecular Dynamics Simulation. Program and Book of Abstracts: 13th Meeting of the European Society of Sonochemistry, Lviv, Ukraine, 1-5.07.2012. , 129−130.
1.1.
2011
Ploom, A.; Tuulmets, A.; Järv, J. (2011). Structure-reactivity relationships in organosilicon chemistry revisited. Central European Journal of Chemistry, 9 (5), 910−916. DOI: 10.2478/s11532-011-0075-x.
5.2.
2011
Piiskop, S.; Salmar, S.; Tuulmets, A. (2011). Sonokeemia allpool 1kHz [Sonochemistry below 1kHz]. Teaduskonverentsi teesid: Eesti XXXII Keemiapäevad, Tartu, 14-15.04.2011. Tartu Ülikooli Kirjastus, 79.
5.2.
2011
Ploom, A.; Tuulmets, A. (2011). Grignard Reaction with Organosilanes. The 13th European Symposium on Organic Reactivity (ESOR), Tartu, Estonia, 11.09.-16.09.
1.1.
2010
Ploom, A.; Tuulmets, A.; Järv, J. (2010). Steric parameters for substituents bound to atoms of silicon and some other elements of the third period. Phosphorus Sulfur and Silicon and the Related Elements, 185 (12), 2503−2510. DOI: 10.1080/10426501003713106.
1.1.
2010
Tuulmets, A.; Cravotto, G.; Salmar, S.; Järv, J. (2010). Sonochemistry of Homogeneous Ionic Reactions. Mini-Reviews in Organic Chemistry, 7 (3), 204−211.
1.1.
2010
Tuulmets, Ants; Ploom, Anu; Panov, Dmitri; Järv, Jaak (2010). Selectivity in the Grignard Reaction with Silanes. Synlett, 2, 291−293. DOI: 10.1055/s-0029-1219167.
2.1.
2010
Tuulmets, A.; Salmar, S.; Järv, J. (2010). Sonochemistry in water organic solutions. New York: Nova Science Publishers.
3.1.
2010
Tuulmets, Ants; Salmar, Siim; Järv, Jaak (2010). Ultrasound and hydrofobic interactions in solutions. In: Nowak, Filip M. (Ed.). Sonochemistry: Theory, Reactions and Synthesis, and Applications (129−156).. Nova Science Publisher Inc..
5.2.
2010
Ploom, Anu; Tuulmets, Ants (2010). Grignard Reaction with Silanes. 9th International Symposium On Carbanion Chemistry; Florence, Italy; July 20-24.
5.2.
2010
Salmar, S.; Piiskop, S.; Tuulmets, A. (2010). Sonochemistry below 1 kHz: a fantasy or reality? 12th Meeting of the European Society of Sonochemistry; Chania, Crete, Greece; May 30-June 03 2010. , 113.
5.2.
2010
Piiskop, S; Salmar, S: Tuulmets, A. (2010). Kõrgenergia ultraheli kui uudne vahend (bio)orgaanilises tehnoloogias. Teaduskonverentsi teesid: XXXI Eesti Keemiapäevad, Tallinn, 2010. , 63−63.
1.1.
2009
Tuulmets, A.; Järv, J.; Tenno, T.; Salmar, S. (2009). Significance of hydrophobic interactions in water-organic binary solvents. Journal of Molecular Liquids, 148, 94−98.
1.1.
2009
Ploom, A.; Tuulmets, A. (2009). A novel insight into the inductive effect in silicon chemistry. Journal of Organometallic Chemistry, 694 (3), 313−315. DOI: 10.1016/j.jorganchem.2008.12.001.
3.3.
2009
Tamm, Lembi ; Tamm, Tarmo; Tuulmets, Ants (2009). Keemia mõisted gümnaasiumile. Eesti-vene-eesti sõnastik. Timotheus, Heiki (_EditorsAbbr). .. Tartu: Tartu Riiklik Ülikool.
5.2.
2009
Tuulmets, A.; Salmar, S.; Cravotto, G. (2009). A quarts horn a successful STSM project, and the domino effect. COST D32 Action Final Meeting, Book of abstracts: COST D32 Action Final Meeting "Chemistry in High-Energy Microenvironments"; Krakow, Poland; March 29 – April 1, 2009. Ed. Dariusz Bogdal. Krakow, Poland: B-C Studio s.c., ul. Wielicka 28, 30-552 Krakow, Poland, 74−75.
5.2.
2009
Salmar, S.;Tuulmets, A.; Cravotto, G.; Piiskop, S. (2009). Why are ionic reactions in pure water affected by ultrasound? COST D32 Action Final Meeting, Book of abstracts: COST D32 Action Final Meeting "Chemistry in High-Energy Microenvironments"; Krakow, Poland; March 29 – April 1, 2009. Ed. Bogdal, D. Krakow, Poland: B-C Studio s.c., ul. Wielicka 28, 30-552 Krakow, Poland, 80−81.
5.2.
2009
Salmar, S.; Tuulmets, A.; Piiskop, S. (2009). New prospective applications of power ultrasound in (bio) organic technologies. GPE-EPIC congress; Venice, Italy; June 14-17, 2009.
6.2.
2009
Tamm, L.; Tamm, T.; Tuulmets, A. (2009). Keemia mõisted gümnaasiumile. Eesti - vene - eesti sõnastik. Tartu: Tartu Ülikooli Kirjastus.
1.1.
2008
Tuulmets, A.; Järv, J.; Salmar, S.; Cravotto, G. (2008). Ultrasonic detection of hydrophobic interactions: a quantitative approach. Journal of Physical Organic Chemistry, 21 (11), 1002−1006. DOI: 10.1002/poc.1415.
1.1.
2008
Ploom, A.; Panov, D.; Järv, J.; Tuulmets, A. (2008). Rate and equilibrium constants for Grignard reaction with alkoxysilanes. Journal of Organometallic Chemistry, 693 (13), 2351−2354.
5.2.
2008
Siim Salmar, Ants Tuulmets, Giancarlo Cravotto, Jaak Järv (2008). Why are ionic reactions in pure water affected by ultrasound? Program and book of abstract: 11 th Meeting of the European Society of Sonochemistry, La Grande-Motte; France; June 1-5, 2008.
1.1.
2007
Golubev, O.; Panov, D.; Ploom, A.; Tuulmets, A.; Nguyen, Binh T. (2007). Quantitative substituent effects in the Grignard reaction with silanes. Journal of Organometallic Chemistry, 692 (17), 3700−3705. DOI: 10.1016/j.jorganchem.2007.05.009.
1.1.
2007
Tuulmets, A.; Hagu, H.; Salmar, S.; Cravotto, G.; Järv, J. (2007). Ultrasonic evidence of hydrophobic interactions. Effect of ultrasound on benzoin condensation and some other reactions in aqueous ethanol. The Journal of Physical Chemistry B, 111 (12), 3133−3138.
1.1.
2007
Hagu, H.; Salmar, S.; Tuulmets, A. (2007). Impact of ultrasound on hydrophobic interactions in solutions: ultrasonic relation of benzoin condensation. Ultrasonics Sonochemistry, 14 (4), 445−449. DOI: 10.1016/j.ultsonch.2006.09.012.
1.2.
2007
Piiskop, S.; Hagu, H.; Järv, J.; Salmar, S.; Tuulmets, A. (2007). Sonication effects on ester hydrolysis in alcohol-water mixtures. Proceedings of the Estonian Academy of Sciences. Chemistry, 56 (4), 199−206.
1.1.
2006
Panov, D.; Ploom, A.; Tuulmets, A. (2006). Steric effects of alkylmagnesium chlorides in the Grignard reaction with silanes. Phosphorus Sulfur and Silicon and the Related Elements, 181 (12), 2807−2816.
1.1.
2006
Ploom, A.; Panov, D.; Tuulmets, A. (2006). Steric effects of alkyl substituents in silicon chemistry. Arkivoc, 5, 37−42.
1.1.
2006
Panov, D.; Tuulmets, A.; Nguyen, B. T. (2006). Impact of reaction products on the Grignard reaction with silanes and ketones. Journal of Organometallic Chemistry, 691 (19), 4076−4079.
1.1.
2006
Salmar, Siim; Cravotto, Giancarlo; Tuulmets, Ants; Hagu, Hannes (2006). Effect of ultrasound on the base-catalyzed hydrolysis of 4-nitrophenyl acetate in aqueous ethanol. The Journal of Physical Chemistry B, 110 (11), 5817−5821.
5.2.
2006
Salmar, S.; Cravotto, G.; Tuulmets, A.; Hagu, H. (2006). Effect of Ultrasound on Hydrolysis of 4-Nitrophenyl Acetate. A Kinetic Anomaly Associated with the Use of Titanium Horns. 10th Meeting of the European Society of Sonochemistry; Hamburg, Germany; June 4-8, 2006. 61.
5.2.
2006
Hagu, H.; Salmar, S.; Tuulmets, A. (2006). Ultrasonic Revelation of Hydrophobic Interactions. 10th Meeting of the European Society of Sonochemistry; Hamburg, Germany; June 4-8, 2006. 48.
1.1.
2005
Simuste, H.; Panov, D.; Tuulmets, A.; Nguyen, BT. (2005). Formation of phenylmagnesium halides in toluene. Journal of Organometallic Chemistry, 690 (12), 3061−3066.
1.2.
2005
Ploom, A.; Panov, D.; Tuulmets, A. (2005). Rate and equilibtrium constants for the Grignard reaction with alkoxysilanes. Proceedings of the Estonian Academy of Sciences. Chemistry, 54 (3), 165−171.
1.1.
2004
Tammiku-Taul, J.; Burk, P.; Tuulmets, A. (2004). Theoretical study of magnesium compounds: The Schlenk equilibrium in the gas phase and in the presence of Et2O and THF molecules. The Journal of Physical Chemistry A, 108 (1), 133−139.
1.1.
2004
Tuulmets, A.; Tammiku-Taul, J.; Burk, P. (2004). Computational study of the Grignard reaction with alkynes. Journal of Molecular Structure THEOCHEM, 674, 233−239.
1.1.
2004
Tuulmets, A.; Nguyen, BT.; Panov, D. (2004). Grignard reaction with chlorosilanes in THF: A kinetic study. Journal of Organic Chemistry, 69 (15), 5071−5076.
1.1.
2003
Sassian, M.; Tuulmets, A. (2003). Solvation effects in the Grignard reaction with carbonyl compounds. Helvetica Chimica Acta, 86 (1), 82−90.
1.1.
2003
Tuulmets, A.; Panov, D.; Sassian, M. (2003). On the mechanism derived from kinetic solvent effects of Grignard reactions with silanes. Tetrahedron Letters, 44 (20), 3943−3945.
1.1.
2003
Tuulmets, A.; Nguyen, BT.; Panov, D.; Sassian, M.; Jarv, J. (2003). Kinetics of the grignard reaction with silanes in diethyl ether and ether-toluene mixtures. Journal of Organic Chemistry, 68 (26), 9933−9937.
1.1.
2003
Tuulmets, A.; Salmar, S.; Hagu, H. (2003). Effect of ultrasound on ester hydrolysis in binary solvents. The Journal of Physical Chemistry B, 107 (46), 12891−12896.
1.1.
2002
Sassian, M.; Panov, D.; Tuulmets, A. (2002). Grignard reagents in toluene solutions. Applied Organometallic Chemistry, 16 (9), 525−529.
1.1.
2002
Tuulmets, A.; Pallin, V.; Tammiku-Taul, J.; Burk, P.; Raie, K. (2002). Solvent effects in the Grignard reaction with alkynes. Journal of Physical Organic Chemistry, 15 (10), 701−705.
1.1.
2002
Pallin, V.; Tuulmets, A.; Raie, K. (2002). Reactivity of PhMgBr towards an alkyne in THF and non-donating solvents. Main Group Metal Chemistry, 25 (5), 297−300.
1.1.
2002
Sassian, M.; Tuulmets, A. (2002). Reactions of partially solvated Grignard reagents with benzaldehyde. Main Group Metal Chemistry, 25 (12), 745−748.
1.1.
2001
Tuulmets, A.; Salmar, S. (2001). Effect of ultrasound on ester hydrolysis in aqueous ethanol. Ultrasonics Sonochemistry, 8 (3), 209−212.
1.1.
2001
Tammiku, J.; Burk, P.; Tuulmets, A. (2001). 1,10-phenanthroline and its complexes with magnesium compounds. Disproportionation equilibria. The Journal of Physical Chemistry A, 105 (37), 8554−8561.
1.1.
2000
Tuulmets, A.; Talvik, AT. (2000). Activation energies of aminolysis of aliphatic esters in aprotic media. ACH-Models in Chemistry, 137 (1), 111−119.
1.1.
2000
Pallin, V.; Tuulmets, A. (2000). Grignard reaction with acetylene in THF. Main Group Metal Chemistry, 23 (3), 179−182.
1.1.
2000
Tammiku, J.; Burk, P.; Tuulmets, A. (2000). UV-vis spectrum of the 1,10-phenanthroline-ethylmagnesium bromide complex. An experimental and computational study. Main Group Metal Chemistry, 23 (5), 301−305.
1.1.
1999
Tuulmets, A.; Raik, P. (1999). Ultrasonic acceleration of ester hydrolyses. Ultrasonics Sonochemistry, 6, 85−87.
1.1.
1999
Tuulmets, A.; Sassian, M. (1999). Reactions of partially solvated Grignard reagents with a ketone. Journal of Organometallic Chemistry, 586 (2), 145−149.
1.1.
1999
Pallin, V.; Otsa, E.; Tuulmets, A. (1999). Mechanism of the reaction of acetylene with Grignard reagents. Journal of Organometallic Chemistry, 590 (2), 149−152.
1.1.
1999
Tuulmets, A.; Panov, D. (1999). Solvation effects in partially solvated Grignard reagents. Journal of Organometallic Chemistry, 575 (2), 182−186.
1.1.
1999
Pallin, V.; Tuulmets, A. (1999). Complexes PhMgBr center dot nMgBr(2)center dot mNEt(3) in the reaction with acetylene. Journal of Organometallic Chemistry, 584 (1), 185−189.
1.1.
1999
Panov, D.; Tuulmets, A. (1999). Are bidentate ligands always acting as bidentate? The case of Grignard reagents. Main Group Metal Chemistry, 22 (5), 297−300.
1.1.
1999
Talvik, AT.; Tuulmets, A.; Vaino, E. (1999). Kinetics and mechanism of aminolysis of aliphatic esters in aprotic solvents. Journal of Physical Organic Chemistry, 12 (10), 747−750.
1.1.
1997
Tuulmets, A.; Pallin, V. (1997). Reactions of partially solvated n-butylmagnesium chloride with diisopropyl ketone in toluene. Main Group Metal Chemistry, 20 (2), 85−87.
1.1.
1997
Tuulmets, A. (1997). Ultrasound and polar homogeneous reactions. Ultrasonics Sonochemistry, 4 (2), 189−193.
1.1.
1997
Tuulmets, A.; Kirss, M. (1997). Rate data from induction period determinations for alkyl- and phenylmagnesium bromide formation. Main Group Metal Chemistry, 20 (5), 345−349.
1.1.
1997
Tuulmets, A.; Mikk, M.; Panov, D. (1997). Schlenk equilibrium in toluene solutions of Grignard reagents. Main Group Metal Chemistry, 20 (1), 1−5.
1.1.
1996
Tuulmets, A.; Mikk, M.; Panov, D. (1996). Partially solvated alkylmagnesium chlorides in toluene. Journal of Organometallic Chemistry, 523 (2), 133−138.
1.1.
1995
Tuulmets, A.; Kaubi, K.; Heinoja, K. (1995). Influence of sonication on grignard-reagent formation. Ultrasonics Sonochemistry, 2 (2), S75−S78.
1.1.
1990
Tuulmets, A.; Heinoja, K. (1990). Influence of inhibitors on initiation of the grignard reaction - nature of induction period. Organic Reactivity, 27, 42−62.
1.1.
1990
Tuulmets, A.; Heinoja, K. (1990). Influence of sonication on the induction period of the grignard reaction. Organic Reactivity, 27, 63−73.
1.1.
1988
Tuulmets, A.; Horak, M.; Ong, A.; Limberg, M. (1988). The grignard-reagent catalyzed grignard reaction. Organic Reactivity, 25 (1), 116−124.
1.1.
1987
Haldna, UL.; Juga, RJ.; Tuulmets, AV.; Juriado, TJ. (1987). Influence of substituent on rate and equilibrium-constants by means of spectral-isolation factor-analysis. Journal of the Chemical Society-Perkin Transactions 2, 11, 1559−1562.
1.1.
1987
Tuulmets, A.; Horak, M.; Hansen, E.; Palm, V. (1987). Some structure-reactivity relationships for alkylbromides in the grignard reaction. Organic Reactivity, 24 (4), 412−424.
1.1.
1986
Tuulmets, A.; Horak, M.; Kaubi, K. (1986). Ultrasonic acceleration of grignard-reagent formation - a kinetic-study. Organic Reactivity, 23 (4), 397−402.
1.1.
1985
Tuulmets, A.; Horak, M.; Aaresild, E.; Sarv, K. (1985). Influence of small additions of organic-bases on the kinetics of grignard-reagent formation in toluene. Organic Reactivity, 22 (4), 460−466.
1.1.
1985
Tuulmets, A.; Horak, M.; Sarv, K.; Aaresild, E. (1985). Interaction of butyl bromide with magnesium in presence of butyl ether - novel details of the reaction-mechanism. Organic Reactivity, 22 (3), 332−340.
1.1.
1985
Tuulmets, A.; Horak, M.; Pill, E.; Riikeja, A. (1985). Kinetics of formation of grignard-reagent with small additions of ethyl ether. Organic Reactivity, 22 (1), 93−101.
1.1.
1983
Uri, A.; Tuulmets, A.; Palm, V. (1983). Trans-esterification of esters of carboxylic-acids by titanium alcoholates. 2. Trans-esterification of esters of aromatic-acids. Organic Reactivity, 20 (1), 122−131.
1.1.
1983
Uri, A.; Tuulmets, A. (1983). Trans-esterification of esters of carboxylic-acids by titanium alkoxides. 4. Solvent effects upon trans-esterification kinetics of butyl chloroacetate by sec-butyl orthotitanate. Organic Reactivity, 20 (4), 578−596.
1.1.
1982
Tuulmets, A.; Horak, M.; Kyopere, T.; Ruotsi, J. (1982). Kinetics of the reaction of tetraethoxysilane with ethylmagnesium chloride in ethyl ether and in the mixtures of ether with toluene. Organic Reactivity, 19 (1), 102−119.
1.1.
1981
Tuulmets, A.; Horak, M.; Jakob, E.; Vapper, M. (1981). Kinetics of formation of normal-butylmagnesium halides in mixtures of toluene with organic-bases. Organic Reactivity, 18 (2), 225−245.
1.1.
1981
Uri, A.; Tuulmets, A. (1981). Trans-esterification of esters of carboxylic-acids by titanium alcoholates. 1. Trans-esterification of normal-butyl chloroacetate by sec-butylorthotitanate in heptane. Organic Reactivity, 18 (2), 179−185.
1.1.
1980
Tuulmets, A.; Kalbus, M. (1980). Catalytic effect of triethylamine on enolization of ketones by phenylmagnesium bromide. Organic Reactivity, 17 (1), 112−119.
1.1.
1980
Uri, A.; Tuulmets, A. (1980). On the interpretation of experimental-data on the alkaline-hydrolysis rate of esters in aqueous - ethanol solutions. Organic Reactivity, 17 (2), 239−243.
1.1.
1980
Horak, M.; Tuulmets, A.; Vaher, M.; Vija, S. (1980). Solvent effects on the reaction-kinetics of dialkylmagnesium with epexides. Organic Reactivity, 17 (2), 215−232.
1.1.
1979
Tuulmets, A.; Palm, N.; Liitmaa, M.; Rang, S. (1979). Kinetics of the reaction of phenyl acetylene with organo-magnesium compounds. Organic Reactivity, 16 (4), 440−445.
1.1.
1978
Uri, A.; Tuulmets, A.; Laasik, T. (1978). Negative activation-energy of aminolysis of isobutyltrichloroacetate. Organic Reactivity, 15 (4), 571−575.
1.1.
1978
Kurrikoff, S.; Tuulmets, A. (1978). Reaction-kinetics of acetylenic-compounds with substituted magnesium diphenyls. Organic Reactivity, 15 (1), 124−132.
1.1.
1977
Palm, N.; Tuulmets, A. (1977). Kinetic study of reaction of triphenylaluminum with benzophenone. Organic Reactivity, 14 (2), 246−262.
1.1.
1977
Pallin, V.; Soova, H.; Tuulmets, A. (1977). Kinetics of catalytic reaction of acetylene with phenylmagnesium bromide in presence of magnesium bromide and large additions of triethylamine. Organic Reactivity, 14 (1), 88−100.
1.1.
1977
Uri, A.; Tuulmets, A. (1977). Kinetics of methanolysis of isobutyl-chloroacetate. Organic Reactivity, 14 (3), 409−416.
1.1.
1976
Pallin, V.; Laane, A.; Tammaru, U.; Tuulmets, A. (1976). Catalytic action of organic-bases on reaction of acetylene with phenylmagnesium bromide. Organic Reactivity, 13 (1), 139−149.
1.1.
1976
Lopp, M.; Otsa, E.; Pallin, V.; Tuulmets, A. (1976). Kinetics and mechanism of reaction of acetylene with phenylmagnesium bromide in presence of triethylamine and without a catalyst. Organic Reactivity, 13 (4), 506−522.
1.1.
1976
Kirso, U.; Shevchuk, I.; Tuulmets, A.; Gubergritis, M.; Lille, Y. (1976). Kinetics of initiated oxidation of substituted phenols in ethyl-alcohol. Organic Reactivity, 13 (3), 345−350.
6.09.2021

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